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A City on Mars: Reality kills space settlement dreams
(arstechnica.com)
This is a most excellent place for technology news and articles.
We can't breathe oxidized iron or carbon dioxide. We'd need to convert it into breathable oxygen and the mechanism would have to be foolproof and have redundancies. And that still leaves plenty of other problems.
But my main point was to everyone in this thread criticizing the authors for being pessimists. This isn't just naysaying or complaining. The authors are pointing out all of the necessary research we still have to do before a space colony can be feasible.
NASAs rover has already successfully tested a carbon dioxide to oxygen conversion system, MOXIE.
https://mars.nasa.gov/mars2020/spacecraft/instruments/moxie/
https://www.nasa.gov/news-release/nasas-perseverance-mars-rover-extracts-first-oxygen-from-red-planet/
If they can do it on a rover, it's pretty trivial to scale that up to an industrial scale.
In the first link you provided, NASA themselves say we'd need a 25,000 watt power plant to scale that up. That's not trivial.
Again, what the authors are pointing out is that space colonization is probably scientifically possible, but will take a lot of research and then investment. MOXIE is a great tech demo, but its not a solution by itself.