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Alternative to Google Photos
(self.foss)
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Pending on your use case, it's probably fine; If you just want to have your own photos backup/home cloud server, it will probably serve you very well. This particular model is not very powerful (though most synology nas enclosures aren't super beefy in general), so as long as you arent expecting it to be a work horse for any heavy duty calculations (transcoding in plex, hosting VMs or docker containers, etc.), it will probably work out great. It would probably also struggle if you expect to have lots of user (10+) using it frequently.
I want my own person cloud storage I could access from anywhere in the world with some Google Photos functionalities and probably some tinkering but not a lot. It would be just me and my partner using it, but mostly just me. Maybe install a PiHol? Is that an option? What other possibilities are there?
If that's the case you'll probably be well served with that model you linked above.
As for what your options are, there's a ton of functionality you can add to them through apps and can even practically run whole VMs on them. Probably not a great idea with the above model but the option is there.
Technically you could set it up as a pihole as well, yes, you'd need to install the docker service and load a DNS service and pihole into it, you can probably find some guides online how to do so.