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Anon questions physics
(sh.itjust.works)
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Each individual molecule did reach an excited state and entered the air, as the air molecules themselves are already highly excited. Also, if the air already has enough moisture then the moisture molecules in the air can accumulate on surfaces that are cold enough that they lose their excited state energy, and a puddle could remain even in warm temperatures because as water leaves the puddle more can also accumulate there.
Also diffusion and vapor pressure and latent heat - reality is messy